Carbon and oxygen isotopes of Maastrichtian-Danian shallow marine carbonate: Yacoraite Formation, northwestern Argentina

MARQUILLAS, R.; SABINO, I.; SIAL, A.,; DEL PAPA, C.,; FERREIRA, F.; MATTHEWS, S

JOURNAL OF SOUTH AMERICAN EARTH SCIENCES

Elsevier

Año: 2007 vol. 23 p. 304 - 320

0895-9811

The Maastrichtian–Danian limestones of the Yacoraite Formation (northwestern Argentina) show carbon and oxygen isotopic values consistent with shallow marine conditions. The members of the formation respond to different sedimentary environments and are characterised by distinctive stable isotopes and geochemistry. The basal Amblayo Member is composed of high-energy dolomitic limestones and limestones with positive isotopic values (+2‰ d13C, +2‰ d18O). The top of the member reveals an isotopic shift of d13C (-5‰) and d18O (-10‰), probably related to a descent in the sea level. The sandy Güemes Member has isotopically negative (-2‰ d13C, -1‰ d18O) limestones, principally controlled by water mixing decreased organic productivity, and compositional changes in the carbonates. The isotopically lighter limestones are calcitic, with a greater terrigenous contribution and different geochemical composition (high Si-Mn-Fe-Na, low Ca-Mg-Sr). These isotopic and lithological changes relate to the Cretaceous–Palaeogene transition. The Alemanía Member, composed of dolomitic limestones and pelites, represents a return to marine conditions and shows a gradual increase in isotopic values, reaching values similar to those of the Amblayo Member. The Juramento Member, composed of stromatolite limestones, shows isotopic variations that can be correlated with the two well-defined, shallowing upward sequences of the member.