One-Step Synthesis of CaO-ZnO Efficient Catalyst for Biodiesel Production

TOLEDO ARANA, JAVIER; TORRES, JUAN JOSÉ; ACEVEDO, DIEGO F.; ILLANES, CRISTIAN O.; OCHOA, NELIO A.; PAGLIERO, CECILIA L.

International Journal of Chemical Engineering

Hidawi

Lugar: London; Año: 2019 vol. 2019 p. 1 - 7

1687-806X

Biodiesel is the best candidate for fuel oil replacement, and to obtain it, heterogeneous catalysts offer large advantages: they can be separated from the product and reused. This work reviews a novel one-step synthesis of CaO-ZnO catalytic particles suitable for biodiesel production. *e catalyst is synthesized using an original simple method that involves mixing of ZnO with CaCO3 and subsequent calcination. *e CaO-ZnO microparticles obtained present an average size of 2 μm. *is material shows the characteristic crystallographic cubic structure of CaO and the hexagonal phase of ZnO. *e temperature-programmed reduction experiment evidences an interaction between CaO and ZnO. Moreover, the infrared spectroscopy shows typical bands of these compounds. *e catalyst shows high biodiesel yield, up to 73% in the first cycle and 64% in the second one. In this work, the synthesis of an efficient CaO-ZnO catalyst with a huge potential is revealed, which could be an economic alternative to produce biodiesel.