INVESTIGADORES
GENNARI Fabiana Cristina
artículos
Título:
A novel polymorph of gadolinium tetrahydroborate produced by mechanical milling.
Autor/es:
J. ANDRADE GAMBOA; J. A. PUSZKIEL; L. FERNÁNDEZ ALBANESI; F. C. GENNARI
Revista:
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Año: 2010 vol. 35 p. 10324 - 10328
ISSN:
0360-3199
Resumen:
Gadolinium tetrahydroborate produced by mechanochemical processing of LiBH4-3GdCl3mixture exhibits a structural transformation at 484 K. The high-temperature structure hasa type cubic structure Gd(BH4)3 (a =11.418 A), which is isostructural with the one recentlyreported for Ce(BH4)3. This new phase remains upon heating up to 503 K. Combination ofthermal hydrogen desorption, DSC, PXRD and FTIR allows to determine that the thermaldecomposition of high-temperature structure Gd(BH4)3 starts above 503 K and leads to3.1 wt% of hydrogen release obtaining mainly GdH2 as final decomposition product.
