Hydriding/dehydriding behavior of Mg2CoH5 produced by reactive mechanical milling

I. GONZÁLEZ FERNÁNDEZ; G. O. MEYER; F. C. GENNARI

JOURNAL OF ALLOYS AND COMPOUNDS

Elsevier

Lugar: Amsterdam; Año: 2008 vol. 464 p. 111 - 117

0925-8388

Complex Mg2CoH5 hydride was obtained by a combined procedure that included a milling stage of a 2Mg?Co mixture under argon followed by reactive mechanical alloying (RMA) under hydrogen, both at room temperature. During RMA, MgH2 is produced at short milling times (10 h) and Mg2CoH5 (50 wt%) after 90 h. Improvement in the yield and the formation times could be associated with both refinement of microstructure and enhancement of intermixing of Mg?Co during pre-milling stage. DSC studies of Mg2CoH5 phase produced by RMA show that the starting decomposition temperature is about 205 ◦C. Absorption and desorption PCIs were determined under static (300 ◦C) and dynamic (230?330 ◦C) conditions. An important hysteresis and two plateaus were observed and correlated with formation/decomposition of Mg2CoH5 (high-pressure plateau) and Mg6Co2H11 (low-pressure plateau) hydrides. For comparing hydrogen sorption kinetics, Mg2CoH5 (65 wt%) was also obtained by a sintering method at 410 ◦C and 6.0MPa of hydrogen pressure. Absorption was very fast in the temperature range of 150?350 ◦C, independently of synthesis procedure. However, desorption curves showed a better behavior for RMA powders. MgCo was observed after decomposition of Mg2CoH5 under particular thermal treatments, while MgCo2 phase was not detected. The results of this study reinforce the idea that kinetics factors related with atomic mobility play a key role in the formation of Mg?Co intermetallics.