Interparticle interactions effects on the magnetic order in surface of Fe3O4 nanoparticles

E. LIMA JR.; J. VARGAS; H.R. RECHENBERG; R.D. ZYSLER

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY

ASP

Lugar: New York; Año: 2008 vol. 8 p. 5913 - 5920

1533-4880

We report interparticle interactions effects on the magnetic structure of the surface region in Fe3O4 nanoparticles. For that, we have studied a desirable system composed by Fe3O4 nanoparticles with <d> = 9.3 nm and a narrow size distribution. These particles present an interesting morphology constituted by a crystalline core and a broad (∼50% vol.) disordered superficial shell. Two samples were prepared with distinct concentrations of the particles: weakly-interacting particles dispersed in a polymer and strongly-dipolar-interacting particles in a powder sample. M(H,T) measurements clearly show that strong dipolar interparticle interaction modifies the magnetic structure of the structurally disordered superficial shell. Consequently, we have observed drastically distinct thermal behaviours of magnetization and susceptibility comparing weakly-and strongly-interacting samples for the temperature range 2 K < T <300 K. We have also observed a temperature-field dependence of the hysteresis loops of the dispersed sample that is not observed in the hysteresis loops of the powder one.