EFFECT OF PROCESS CONDITIONS ON PHYSICOCHEMICAL AND ELECTRICAL CHARACTERISTICS OF DENIM-BASED ACTIVATED CARBON CLOTHS

M. E. RAMOS; P. BONELLI; J. GONZALEZ; A. L. CUKIERMAN

INDUSTRIAL & ENGINEERING CHEMICAL RESEARCH

AMERICAN CHEMICAL SOCIETY

Lugar: COLUMBUS OH., USA; Año: 2007 vol. 46 p. 1167 - 1173

0888-5885

Activated carbon cloths (ACCs) from denim fabric were developed by phosphoric acid activation in an inert atmosphere. The effect of acid concentration (5-15 wt %) and final thermal treatment temperature (600-950 C) on yield, chemical characteristics (elemental composition, ash, total acidity), porosity development, morphology, and electrical properties of the resulting ACCs were examined. Noticeable changes in the thermal behavior of the precursor due to acid impregnation were detected from thermogravimetric measurements using comparative samples of raw and acid-treated denim. ACCs properties were dependent on a combined effect of the conditions employed, though the temperature exerted a major influence. The ACCs prepared with 10 wt % acid concentration at 950 C showed maximum BET surface area (1055 m2/g) and total pore volume (0.53 cm3/g), and well-preserved fibers integrity. Almost all the denim-derived ACCs were electrically conductive, following ohmic behavior. Increasing the final temperature from 600 to 800 C led to a substantial change in electrical conductivity. The ACCs were heated by Joule effect, attaining surface temperatures in the range 300-500 K. Electrical resistivity of the ACCs was found to depend on the extent of porosity development.