INVESTIGADORES
MATA Ernesto Gabino
artículos
Título:
Bis (tributyltin) oxide. A mild, neutral and selective reagent for cleavage of esters. Scope and limitation of the reaction
Autor/es:
SALOMON, CLAUDIO J.; MATA, ERNESTO G.; MASCARETTI, ORESTE A.
Revista:
TETRAHEDRON LETTERS
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Año: 1991 vol. 32 p. 4239 - 4242
ISSN:
0040-4039
Resumen:
Bis(tributyltin)oxide acts as a mild, neutral and chemoselective ester cleavage reagent for a variety of carboxylic esters with good to excellent yields. The acyl-oxygen cleavage mechanism of (−)-(1R) menthyl acetate is discussed.
