Solid-phase cross metathesis: The effect of the non-immobilized olefin and the precatalyst on the intrasite interference

POEYLAUT-PALENA, A.A.; MATA, E. G.

ARKIVOC - ONLINE JOURNAL OF ORGANIC CHEMISTRY

ARKAT USA INC

Año: 2010 vol. iii p. 216 - 227

1551-7004

We have developed a study on the factors that influence the intrasite interactions in the cross metathesis on solid support. When such interactions are possible, the outcome of the intrasite by-product depends on the non-immobilized olefin and the precatalyst used. The comparatively poor reactivity of first generation Grubbs precatalyst makes the easier intrasite coupling to succeed