INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Anisotropy and relaxation processes of uniaxially oriented CoFe2O4 nanoparticles dispersed in PDMS
Autor/es:
P. S. ANTONEL; R. M. NEGRI; A. G. LEYVA; G. A. JORGE
Revista:
PHYSICA B - CONDENSED MATTER
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Año: 2012 vol. 407 p. 3165 - 3165
ISSN:
0921-4526
Resumen:
When a uniaxial magnetic field is applied to a non-magnetic dispersive medium filled with magnetic nanoparticles, they auto-assemble into thin needles parallel to the field direction, due to the strong dipolar interaction among them. We have prepared in this way magnetically oriented nanocomposites of nanometer-size CoFe2O4 particles in a polydimethylsiloxane polymer matrix, with 10% w/w of magnetic particles. We present the characteristic magnetic relaxation curves measured after the application of a magnetic field forming an angle alpha with respect to the needle direction. We show that the magnetic viscosity (calculated from the logarithmic relaxation curves) as a function of alpha presents a minimum at alpha = 0, indicating slower relaxation processes associated with this configuration of fields. The results seems to point out that the local magnetic anisotropy of the nanoparticles is oriented along the needles, resulting in the macroscopic magnetic anisotropy observed in our measurements.