INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
N-Butyl pyridinium undecachloro?carbadodecaborate structure and its comparison with similar compounds
Autor/es:
SUÁREZ, S.; FOI, A.; EADY, S.; LARSEN, A.; DOCTOROVICH, F.
Revista:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Editorial:
WILEY-BLACKWELL PUBLISHING, INC
Referencias:
Lugar: Londres; Año: 2011 vol. C67 p. 417 - 420
ISSN:
0108-2701
Resumen:
The title compound, C9H14N+CHB11Cl11 , was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkylpyridiniumand dialkylimidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butylpyridinium cationcounterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds.
