INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Chlorido(4,4 '-dimethoxy-2,2 '-bipyridine)(1,4,7-trimethyl-1,4,7-triazacyclononane)ruthenium(II) perchlorate acetonitrile disolvate and aqua(4,4 '-dimethoxy-2,2 '-bipyridine)(1,4,7-trimethyl-1,4,7-triazacyclononane)ruthenium(II) bis(perchlorate) dihydrate
Autor/es:
VERA, D. B.; OSA CODESIDO, N.; DE CANDIA, A. G.; ALBORES, P.; SLEP, L. D.
Revista:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Editorial:
WILEY-BLACKWELL PUBLISHING, INC
Referencias:
Lugar: Malden MA; Año: 2012 vol. 68 p. 127 - 130
ISSN:
0108-2701
Resumen:
The title complexes, [RuCl(C9H21N3)(C12H12N2O2)]ClO4.2C2H3N, (I), and [Ru(C9H21N3)(C12H12N2O2)(H2O)](ClO4)2.2H2O, (II), display similar structures with the Ru atom in a distorted octahedral environment. In the crystal packing of the chloride complex, (I), the Ru complex molecules are held together in pairs through CH...Cl interactions of the 4,4´-dimethoxy-2,2´-bipyridine and chloride ligands. In the case of the aqua complex, (II), hydrogen bonding affords a tetrameric hydrogen-bonded network. These two structures are the first examples of complexes with the {Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)} motif and an electron-rich substituted 2,2´-bipyridine ligand.
