Thermal Behaviour of 2,5-disustituited Tetrazoles and 1,4-disustituited Triazoles under Flash Vacuum Pyrolysis Conditions

PAOLA L. LUCERO; ELIZABETH L. MOYANO; GLORIA I. YRANZO*

Los Cocos, Córdoba, Argentina

Congreso; 9th Latin American Conference on Physical Organic Chemistry; 2007

The Flash Vacuum Pyrolysis (FVP) is an appropriate technique for the preparation of many organic compounds, isolation of reactive species, and for the mechanistic study of thermal reactions. In this work we studied the thermal behavior of (2E)-3-[2-(4-clorofenil-2H-tetrazoil]-5-acrilaldehido, (2E)-3-[2-(4-metoxifenil-2H-tetrazoil]-5-acrilaldehido,(2E)-3-(1-(4-clorofenil-1H-1,2,3-triazol-4-il)acrilaldehido y de (2E)-3-(1-(4-metoxifenil-1H-1,2,3-triazol-4-il)acrilaldehido under FVP conditions finding interesting differences in their reactivity.