INFIQC   05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Green Synthesis of Dimethyl Isosorbide
Autor/es:
P. TUNDO; F. ARICÒ; G. GAUTHIER; L. ROSSI; A.E. ROSAMILIA; H.S. BEVINAKATTI; R.L. SIEVERT; C. NEWMAN
Revista:
CHEMSUSCHEM
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Lugar: Weinheim; Año: 2010 vol. 5 p. 566 - 570
ISSN:
1864-5631
Resumen:
A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of hydroxyl groups) and to the effect of the hydrogen bonding which increases reactivity of the molecule towards(DMC).