INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Simple and efficient deprotection of 1,3-dithianes and 1,3-dithiolanes by copper(II) salts under solvent-free conditions
Autor/es:
GABRIELA OKSDATH MANSILLA AND ALICIA B. PEÑÉÑORY
Revista:
TETRAHEDRON LETTERS
Editorial:
Elselvier
Referencias:
Año: 2007 vol. 48 p. 6150 - 6154
ISSN:
0040-4039
Resumen:
Aerobic solid state deprotection of 1,3-dithianes and 1,3-dithiolanes of aromatic and aliphatic aldehydes and ketones has been performed in excellent yields by Cu(NO3)2 .2.5H2O in the presence of montmorillonite K-10 clay and sonic waves at room temperature. These dethioacetalizations proceed more slowly but efficiently under catalytic conditions by using a 20% of the copper(II) salt with K-10 clay and sonication.
