INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
FTIR gas kinetic study of the reactions of ozone with a series ofhexenols at atmospheric pressure and 298 K
Autor/es:
RODRIGO G. GIBILISCO; IUSTINIAN BEJAN; IAN BARNES; PETER WIESEN; TERUEL MARIANO ANDRES
Revista:
CHEMICAL PHYSICS LETTERS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2014 vol. 618 p. 114 - 118
ISSN:
0009-2614
Resumen:
Relative rate coefficients of the reactions of O3with (Z)-3-hexen-1-ol, (E)-3-hexen-1-ol and (E)-2-hexen-1-ol have been determined in an environmental chamber with in situ FTIR detection of thereactants at 298 K and 760 Torr. The following rate coefficients (in units of 10−17cm3molecule−1s−1)have been determined: (6.04 ± 0.95) for (Z)-CH2(OH)CH2CH CHCH2CH3; (5.83 ± 0.86) for (E)-CH2(OH)CH2CH CHCH2CH3; (5.98 ± 0.73) for (E)-CH2(OH)CH CH(CH2)2CH3. This is the first kineticstudy for the reactions of O3with (E)-2-hexen-1-ol and (E)-3-hexen-1-ol. Reactivity trends are devel-oped and the atmospheric persistence of these compounds is calculated based on the rate coefficients.
