INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Chemoselectivity Oxidation of Organic Sulfides Catalysed by Fe(III) Complexes
Autor/es:
CLAUDIO O. KINEN, LAURA I. ROSSI*, RITA H. DE ROSSI*
Revista:
APPLIED CATALYSIS A-GENERAL
Editorial:
Elsevier
Referencias:
Año: 2006 vol. 312 p. 120 - 124
ISSN:
0926-860X
Resumen:
Different iron(III) complexes were used as catalysts in sulfoxidation reactions giving excellent yields and a high chemoselectivity. Among the complexes, the best one was a solid b-cyclodextrin-FeBr3 complex. Sulfoxidation takes place with high chemoselectivity in the presence of other groups such as benzaldehyde, benzylic alcohol, benzylic methylene and benzothiazole.
