INFIQC   05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Analysis of arsenic and calcium in soil samples by laser ablation mass spectrometry
Autor/es:
ANA M. BECCAGLIA; CARLOS A. RINALDI; JUAN C. FERRERO
Revista:
ANALYTICA CHIMICA ACTA
Editorial:
Elsevier
Referencias:
Año: 2006 vol. 579 p. 11 - 16
ISSN:
0003-2670
Resumen:
We present an analytical procedure based on laser ablation mass spectrometry (LAMS) in order to detect and quantify arsenic and calcium in soil samples and we analyze the diverse factors that influence the precision of LAMS, such as laser fluence and matrix effect. The results indicate that a Zn matrix is a good choice for the analysis of those metals in soil samples. This work also provides a method for the direct determination of As in soil samples whose concentrations are lower than 100 ppm with a 70 ppm minimum detection limits (MDL). © 2006 Elsevier B.V. All rights reserved. Keywords: Laser ablation; Mass spectrometry; Elemental analysis; Soil sample; Calcium; Arsenic