INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Plasmon-Mediated Photopolymerization Maps Plasmon Fields for Silver Nanoparticles
Autor/es:
KEVIN G. STAMPLECOSKIE; NATALIA L. PACIONI; DAYLE LARSON; JUAN C. SCAIANO
Revista:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2011 p. 9160 - 9163
ISSN:
0002-7863
Resumen:
Visible light exposure of films containing silver nanoparticles (AgNPs) shows that the enhanced field around AgNPs in a thin film containing an azo free radical initiator(AIBN) and a triacrylate selectively cross-links the triacrylate within the plasmonic region around the particles. The crosslinked polymer is less soluble than its precursor and behaves as a solubility switch. After the film is developed with ethanol, polymer-encapsulated nanoparticles are preserved on the surface.The 8-10 nm polymer structure that encapsulates theparticles effectively maps and preserves the morphology of the plasmon field in AgNP-controlled nanostructures.
