INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Computer simulation of reversible electrochemical catalyst promoter dosing
Autor/es:
MARIANA ISABEL ROJAS; MARCELO MARIO MARISCAL; EZEQUIEL PEDRO MARCOS LEIVA
Revista:
ELECTROCHIMICA ACTA
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2010 vol. 55 p. 8673 - 8679
ISSN:
0013-4686
Resumen:
Grand Canonical Monte Carlo simulations were used to study the growth of a Na layer onto aOp(2×2)Pt(1 1 1) surface. At the beginning of the deposition, the film presents a disordered structurewhich becomes progressively ordered as the coverage increases due to the repulsive lateral interactionsbetween the adsorbates. We found some ordered structures like p(16×16), p(14×14) and p(12×12)which appears at coverages l lower than ∼0.007, in all these overlayers the Na adatoms are adsorbedon fcc-hollow sites of the oxide surface.
