PLAPIQUI 05457
PLANTA PILOTO DE INGENIERIA QUIMICA
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
Application of a group-contribution equation of state to model high-pressure phase equilibria of associating systems
Autor/es:
ALFONSINA ESTER ANDREATTA; GLORIA FOCO; SELVA PEREDA; SUSANA BEATRIZ BOTTINI
Lugar:
Foz Iguazú, Brazil,
Reunión:
Congreso; First Iberoamerican Conference on Supercritical Fluids (PROSCIBA); 2007
Institución organizadora:
PLAPIQUI, UNS-CONICET
Resumen:
The group contribution equation of state GCA-EoS has been used to model high-pressure phase equilibria in associating systems. Self- and cross-associating functional groups have been defined and a generalized computational routine has been implemented to quantify association and solvation effects by the interaction between functional groups with one or two associating sites. Results are shown for systems containing dimethyl sulfoxide, thiophene, carboxylic acids, water and carbon dioxide.
