PLAPIQUI   05457
PLANTA PILOTO DE INGENIERIA QUIMICA
Unidad Ejecutora - UE
artículos
Título:
Coupling exothermic and endothermic reactions in an ethanol microreformer for H2 production
Autor/es:
MARISA N. PEDERNERA; EDUARDO LÓPEZ; YANINA M. BRUSCHI; DANIEL O. BORIO
Revista:
CHEMICAL ENGINEERING JOURNAL
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 2016 vol. 294 p. 97 - 104
ISSN:
1385-8947
Resumen:
The steam reforming of ethanol is carried out in a microreactor for hydrogen production. The heat for the endothermic reactions is supplied by means of ethanol combustion in air, which is carried out in contiguous microchannels. The same Pd-based catalyst is assumed to be coated on both reforming and combustion channels. By means of a 1D heterogeneous mathematical model, the influence of the feed temperatures of both streams on the reactor performance is analyzed. The results show that the degree of preheating of both streams has a strong influence on the hydrogen yields and maximum temperatures. The effect of the flowrate and composition of the fuel stream on the hydrogen yields is also studied. Fairly high hydrogen yields were obtained (2.6< rendiemientoH2 < 3.4) with low methane slips, within a feasible range of temperatures for the Pd catalyst (700 < TMAX < 770 ºC) to avoid catalyst deactivation. These maximum temperatures could still be further reduced by means of an optimal selection of the air flowrate and ethanol molar fraction on the fuel side, or using distributed feed of fuel along the reactor length. NOTA DEL EDITOR: > Ms. Ref. No.: CEJ-D-15-06556R1 > Title: Coupling exothermic and endothermic reactions in an ethanol microreformer for H2 production > Chemical Engineering Journal > > Dear Dr. Bruschi, > > I am pleased to confirm that your paper "Coupling exothermic and endothermic reactions in an ethanol microreformer for H2 production" has been accepted for publication in Chemical Engineering Journal. > > You are invited to submit either a figure from your article or other illustration that is representative of your manuscript for possible inclusion on the journal cover. If you wish for your figure or illustration to be considered, please carefully follow the instructions in the Guide for Authors at the link below. Please note that we must receive your submission within 10 days of the date of this letter and that this is a competitive process with only one figure selected out of the many submitted for each issue. Due to the number of submissions, you will only receive further correspondence if your image has been selected.> > See "Submissions of figures for cover" at: http://www.elsevier.com/wps/find/journaldescription.cws_home/601273/authorinstructions#57200. > > Participation is optional and no action is required if you do not wish to submit an image for the cover. > > When your paper is published on ScienceDirect, you want to make sure it gets the attention it deserves. To help you get your message across, Elsevier has developed a new, free service called AudioSlides: brief, webcast-style presentations that are shown (publicly available) next to your published article. This format gives you the opportunity to explain your research in your own words and attract interest. You will receive an invitation email to create an AudioSlides presentation shortly. For more information and examples, please visit http://www.elsevier.com/audioslides.> > Thank you for submitting your work to this journal. > > With kind regards, > Dr. King Lun Yeung > Editor > Chemical Engineering Journal > Professor > Department of Chemical & Biomolecular Engineering Hong Kong University of Science and Technology>