Low-loading Pt/b-Mo2C catalyst for ethanol dissociation. Experimental and theoretical characterization

PRONSATO, ESTELA; JOHÁNEK, VIKTOR; CHASVIN, NILDA; DIEZ, ALEJANDRA; PISTONESI, CAROLINA; SVENDA, PETR; VOLPE, MARÍA ALICIA

PHYSICAL CHEMISTRY CHEMICAL PHYSICS

ROYAL SOC CHEMISTRY

Lugar: CAMBRIDGE; Año: 2021 vol. 23 p. 23567 - 23575

1463-9076

The adsorption and dissociation of ethanol on Pt/β-Mo2C with a low noble metal loading (0.1wt%) is studied in the context of catalytic H2 production from alcohols. X-Ray Diffraction experimental results indicate that Pt modifies the lattice parameters of β-Mo2C. In line with this , density functional theory calculations indicate that Mo-Mo distances are increased due to Pt presence. X-ray Photoelectron Spectroscopy experimental study indicates that the chemical state of both molybdenum and carbon in Pt/β-Mo2C are very different from the ones in the Pt free carbide , also in agreemen with DFT result that the Pt atoms generate a redistribution of charge density in their environment. Temperature Programmed Reaction analysis shows that at temperatures higher than 530K, a two-fold increase in the production of H2, CH4 and C2H6 is observed for Pt/β -Mo2C as compared to β-Mo2C, suggesting a higher catalytic activity for the Pt containing carbyde than for the pristine catalyst. . Besides, H2 production from ethanol on Pt/β-Mo2C presents an activation energy higher (0.64 eV) than the corresponding to pristine molybdenum carbide . In agreement with this experimental result, CI-NEB calculations indicate that the energy barrier linked to the formation of H2 from ethanol increases with the presence of platinum. It is concluded that the low Pt loading notably modifies the catalytic pattern of molybdenum carbide, rendering a high active catalyst for ethanol decomposition.