INIFTA 05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
Efficient and selective N-, S- and O-acetylation in TEAA ionic liquid as catalytic green solvent. Applications in synthetic carbohydrate chemistry.
Autor/es:
LETICIA LAFUENTE; AGUSTÍN PONZINIBBIO; RODOLFO BRAVO; GISELA DÍAZ
Revista:
LETTERS IN ORGANIC CHEMISTRY
Editorial:
BENTHAM SCIENCE PUBL LTD
Referencias:
Lugar: Oak Park; Año: 2016 vol. 13 p. 195 - 200
ISSN:
1570-1786
Resumen:
The ionic liquid triethylammonium acetate (TEAA) was found to be an effi-cient solvent in the acetylation of alcohols, amines, oximes and thiols to their corresponding acetyl compounds using only a 10% excess of acetic anhydride under mild conditions. Moreover TEAA is not only an inexpensive and recyclable solvent but also an anomeric selective catalyst in the per-O-acetylation of sugar moieties.
