INIFTA 05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
Side-On versus End-On Bonding of O2 to the FSO3 Radical: Matrix isolation and ab initio study of FSO5.
Autor/es:
HELMUT BECKERS; PLACIDO GARCIA; HELGE WILLNER; GUSTAVO A. ARGUELLO; CARLOS J. COBOS; JOSEPH S. FRANCISCO
Revista:
ANGEWANDTE CHEMIE
Editorial:
Wiley-VCH Verlag
Referencias:
Lugar: Weinheim; Año: 2007 vol. 46 p. 3754 - 3757
ISSN:
0570-0833
Resumen:
Quantum chemical calculations predict the existence of two almost equal-energy isomers of the FSO5 radical with either side-on or end-on bonding of O2 to FSO3. The structure of this polyoxy radical isolated in solid noble-gas matrices and formed by the reaction of FSO3 with molecular oxygen has now been revealed by IR and UV spectroscopic investigations.
