INIFTA 05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
Experimental Preparation and UV/IR Spectroscopic Characterization of 1,3-dibutanal-1,2,4,5-tetroxane
Autor/es:
D.A. AYALA; J.M. ROMERO; N.L. JORGE; M.E. GÓMEZ VARA; A.H. JUBERT; EDUARDO ALBERTO CASTRO
Revista:
SPECTROCHIMICA ACTA A: MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Referencias:
Año: 2006 vol. 64 p. 717 - 721
ISSN:
0584-8539
Resumen:
Abstract: We report the experimental preparation of the 1,3-butanal-1,2,4,5-tetroxane by
oxidation of glutataldehyde with oxygen peroxide in presence of concentrated
sulfuric acid, following the Bayer and Viller method modified by Jorge et al. The
UV and IR spectra are studied from the experimental and theoretical standpoint.
A rather complete vibrational assignment was performed and the nature of the
electronic transitions was discussed in detail.
