INVESTIGADORES
BLANCO Maria Belen
congresos y reuniones científicas
Título:
Absolute rate coefficients of the reaction of O(3P) atoms with selected chloroethenes
Autor/es:
M. B. BLANCO , P. M. COMETTO, R.A.TACCONE, S.I.LANE AND M.A.TERUEL
Lugar:
Florianópolis, SC, Brazil
Reunión:
Conferencia; 8th Latin American Conference on Physical Organic Chemistry (CLAFQO); 2005
Resumen:
As part of a systematic study of O(3P) atom reactivity, we report in this work absolute rate constants for the reactions of O(3P) with (Z)-CHCl=CHCl, CCl2=CH2, CCl2=CCl2, and CFCl=CHCl measured in a discharge flow tube apparatus coupled with a chemiluminescence detection system to monitor the O(3P) decay at 298 K. The present work was undertaken in order to complete our previous experimental and theoretical studies of O -chloroethenes reactions.