Corrosion of steel drums containing cemented ion-exchange resins as intermediate level nuclear waste

G.S. DUFFO; S.B. FARINA; F.M. SCHULZ

Scientific Basis for Nuclear Waste Management XXXV

Materials Research Society

Lugar: Warrendale; Año: 2012; p. 501 - 506

Ion-exchange resins are used for purification of radioactive liquid waste from nuclear reactors. After exhaustion, resins become intermediate level radioactive waste to be managed. They have to be immobilized before being stored to improve the leach resistance of the waste matrix and to maintain mechanical stability for safety requirements.  The immobilized resins are thus contained in steel drums that can undergo internal corrosion depending on the presence of certain contaminants.  This work shows an study of the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins with different types and contents of aggressive species. Results show that the corrosion depth of the steel drums after a period of 300 years (foreseen life-span of the radioactive waste disposal facility), in the most unfavorable case (high chloride contamination), will be considerably lower than the thickness of the wall of the drums.