CIHIDECAR 12529
CENTRO DE INVESTIGACIONES EN HIDRATOS DE CARBONO
Unidad Ejecutora - UE
artículos
Título:
Photoisomerization of Ionic Liquids Ammonium Cinnamates: One-Pot Synthesis-Isolation of Z-Cinnamic Acids.
Autor/es:
MARIA LAURA SALUM; CECILIA J. ROBLES; ERRA BALSELLS, ROSA
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2010 vol. 12 p. 4808 - 4811
ISSN:
1523-7060
Resumen:
Photoisomerization presents the only direct method for contra-thermodynamic E-Z isomerization of olefins. Synthetic applications of this method have been limited by its reversible nature, which leads to a photostationary-state mixture of both isomers. For the first time a highly efficient one-pot preparation-isolation of solid ionic liquid Z-cinnamic acids by photoisomerization in acetonitrile solution of ionic liquid E-cinnamic acids is described.
