ACID LEACHING OF LiCoO2 FROM LIBs: THERMODYNAMIC STUDY ANDREDUCING AGENT EFFECT

ELIANA G. PINNA; ANDREA A. MARTINEZ; FERNANDO M. TUNEZ; DIEGO S. DRAJLIN; MARIO H. RODRIGUEZ

Revista Mexicana de Ingeniera Qumica

UNIV AUTONOMA METROPOLITANA-IZTAPALAPA

Lugar: México D.F.; Año: 2019 vol. 18 p. 441 - 450

1665-2738

This work shows the results of a comparative hydrometallurgical study of LiCoO2 leaching, obtained from the cathodesof spent lithium-ion batteries (LIBs), with HF and HF/H2O2. The operational parameters researched were H2O2 and HF concentrations, solid-liquid ratio, stirring speed, temperature and reaction time. The experimental results indicated that the best working conditions, with dissolution values close to 100%, were 348 K, 330 rpm, 30 min, 8 g/L, HF 0.6 M and H2O2 0.7 M.Thermodynamic study of the dissociation of HF in aqueous solution and EH-pH diagrams for Li-H2O, Co-H2O and Li-Co-F-H2O systems were performed. The results showed the feasibility of extracting and recovering metals contained in the sample.