Removal of nitrate from drinking water by using PdCu structured catalysts based on cordierite monoliths

MARÍA JAWORSKI; BIBIANA P. BARBERO; GUILLERMO SIRI; MÓNICA CASELLA

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING

BRAZILIAN SOC CHEMICAL ENG

Lugar: BRASIL; Año: 2019 vol. 36 p. 705 - 715

0104-6632

Structured catalysts were prepared, characterized and evaluated in NO3- removal from drinking water. Different suspensions containing a previously optimized PdCu/5wt% ZrO2-Al2O3 powder catalyst (hereinafter PdCu/5ZAp) were prepared and deposited on cordierite monoliths by washcoating. The effect of suspension concentration, the particle size, the immersion number, the use of suspension stabilizer agent, and an alumina pre-coating on the coating adherence and catalytic performance were studied. All the prepared structured catalysts were active for the elimination of NO3- and presented good selectivity to N2 (> 93%) in synthetic water samples. The catalyst performance was related with the amount of deposited catalyst. The highest activity and the best coating adherence were obtained with the structured catalyst prepared by a single immersion in a 14 wt% concentration suspension, which was obtained from the powder catalyst milled for 10 h and stabilized with colloidal alumina.. This catalyst also showed good activity when it was reused for four cycles and when was evaluated with real water samples.