A Novel Electrochromic Polymer Synthesized through Electropolymerization of a New Donor-Acceptor Bipolar System

NUNG-SEN WANG, YEUN-MIN TSAI, TSYR-YUAN HWU, AND KEN-TSUNG WONG, JOSE NATERA, LUIS OTERO, LEONIDES SERENO, AND FERNANDO FUNGO

MACROMOLECULES

AMER CHEMICAL SOC

Año: 2007 vol. 40 p. 4456 - 4463

0024-9297

We have synthesized a novel 9,9¢-spirobifluorene-cored donor-acceptor (D-A) bichromophore system in which the electron-donating (D) moieties are triphenylamine (TPA) and carbazole (CBZ) groups and the electron-withdrawing (A) moieties are 1,3,4-oxadiazole (OXD) groups. The electron-deficient OXD groups efficiently blocked the radical cations delocalization between the two terminal TPA groups, rendering the electropolymerization of the TPA groups feasible. The resulting polymer could be cross-linked further at higher oxidation potentials through electrodimerization occurring at the C3 and C6 positions of the CBZ group. The polymer film obtained exhibited reversible electrochemical oxidation, accompanied by strong color changes with high coloration efficiency and contrast ratio, which could be switched through potential modulation.