Preparation and Characterization of Polybutylene-Succinate/Poly(ethylene-glycol)/Cellulose Nanocrystals Ternary Composites

L. LUDUEÑA; E. FORTUNATI; J. I. MORÁN; V. A. ALVAREZ; V. P. CYRAS; D. PUGLIA; L.B. MANFREDI; M. PRACELLA

JOURNAL OF APPLIED POLYMER SCIENCE

JOHN WILEY & SONS INC

Lugar: New York; Año: 2016 vol. 133 p. 1 - 9

0021-8995

Ternary composites were prepared by twin screw extrusion from polybutylene-succinate (PBS), poly(ethylene-glycol) (PEG) and cellulose nanocrystals (CNC). The aim of the work is to improve the physical-mechanical properties of PBS by the addition of CNC. A PEG/CNC masterbatch was prepared in order to achieve a good dispersion of hydrophilic CNC in the hydrophobic PBS. The influence of the nanoparticle content on the polymer properties was studied.Regarding the thermal properties fractioned crystallization phenomena of PEG was observed during cooling from the melt. No significant nucleating effect of the nanocellulose was observed. The material containing 4wt% of CNC showed the best mechanical performance among the nanocomposites studied due to the combination of high modulus and elongation at break with a low detrimental in strength compared with the PBS/PEG blend. Moreover, no nanocellulose agglomerations were observed in its FESEM micrograph.