INVESTIGADORES
GOMEZ COSTA Marcos Bruno
artículos
Título:
Studies on the synthesis of diacetyl over oxidation zeolite catalysts
Autor/es:
ANUNZIATA, O.; PIERELLA, L.; MARCOS BRUNO GOMEZ COSTA; BELTRAMONE, A.
Revista:
CATALYSIS LETTERS
Editorial:
KLUWER
Referencias:
Año: 2001 vol. 71 p. 1 - 2
ISSN:
1011-372X
Resumen:
Diacetyl (2,3‑butanedione) synthesis from methyl ethyl ketone over oxidation zeolites using 02 as oxidant was studied. Various zeolites with Fe, V and Ti as active sites were employed. VS‑ 1 , Ti‑NCL, Ti‑MCM‑41 and FeBEA type materials were synthesized and characterized by BET, FTIR, XRD, pyridine adsorption and template desorption. The detailed study of the effect of reaction temperature, the effect,of concentration of oxygen and the addition of water was realized. The most active catalyst was zeolites with V as oxidation center.
