INVESTIGADORES
TONETTO Gabriela Marta
artículos
Título:
Pd/Al2O3-cordierite and Pd/Al2O3-Fecralloy monolithic catalysts for the hydrogenation of sunflower oil
Autor/es:
SANCHEZ J.; GONZALES BELLO O.; MONTES M.; TONETTO G.; DAMIANI D.
Revista:
CATALYSIS COMMUNICATIONS
Editorial:
Elsevier
Referencias:
Año: 2009 vol. 10 p. 1446 - 1449
ISSN:
1566-7367
Resumen:
Monolithic catalysts were prepared using cordierite and Fecralloy as substrates, with Pd/Al2O3 catalyst deposited by a washcoating method. The samples were characterized and studied for the partial hydrogenation of sunflower oil at 373 K and 413 kPa. In comparative tests, at equal operating conditions and conversion, the structured catalysts presented a lower trans-isomers formation than the powder catalyst. After three consecutive tests, the ceramic monolith showed no change in activity or selectivity, whereas the metallic monolith showed a partial deactivation (10%), which is attributed to a loss of catalyst.