CIHIDECAR 12529
CENTRO DE INVESTIGACIONES EN HIDRATOS DE CARBONO
Unidad Ejecutora - UE
artículos
Título:
Photoreduction of nitroarenes by formic acid in acetonitrile at room temperature
Autor/es:
ARIEL CORS, SERGIO M. BONESI, ROSA ERRA BALSELLS
Revista:
TETRAHEDRON LETTERS
Editorial:
Elsevier
Referencias:
Lugar: The Netherlands; Año: 2008 vol. 49 p. 1555 - 1558
ISSN:
0040-4039
Resumen:
Abstract
The formic acid-mediated photoreduction of aromatic nitro compounds in room temperature acetonitrile solutions was investigated.
This mild photoreduction can be accomplished in high yield, with wide functional group tolerance and short reaction times (30 min to
1 h), and allows a very clean method for the conversion of nitro arenes to amines. Also, the photoreduction, as a convenient, versatile and
general method, applies efficiently to polycyclic and heterocyclic nitro arenes.
2007 Elsevier Ltd. All rights reserved.2007 Elsevier Ltd. All rights reserved.
