Synthesis, Characterization, and Nanocatalysis Application of Core Shell Superparamagnetic Nanoparticles of Fe 3 O 4 @Pd

A. L. CAPPELLETTI; P. M. UBERMAN; S. E. MARTÍN; M.E. SALETA; H. E. TROIANI; R.D. SÁNCHEZ; R. E. CARBONIO; M. C. STRUMIA

AUSTRALIAN JOURNAL OF CHEMISTRY

CSIRO PUBLISHING

Año: 2015 vol. 68 p. 1492 - 1501

0004-9425

There is a wide number of different synthetic methods to obtain magnetite (Fe3O4) superparamagnetic nanoparticles (SPNPs). However, only a few are able to produce very small and well defined SPNPs with narrow size distribution. We report a modification of the metal-complex decomposition in organic media method in which we replace iron(iii) acetylacetonate (Fe(Acac)3) with an iron?urea complex (Fe-Urea) as metal source for the synthesis. With this modification we were able to obtain small particle sizes with a good control in size distribution. The Fe-Urea complex is easy to prepare with excellent yields. Core?shell nanoparticles are then prepared using palladium(ii) acetylacetonate as a Pd source, to obtain a Pd0 shell stabilised by oleylamine. The core?shell superparamagnetic nanoparticles of Fe3O4@Pd-OA are extensively characterized by FT-IR, powder X-ray diffraction, transmission electron microscopy, UV-vis, thermogravimetric analysis/differential scanning calorimetry, and magnetic susceptibility measurements, and tested in a palladium-catalyzed cross-coupling Suzuki?Miyaura reaction with promising results.