INVESTIGADORES
PIRO Oscar Enrique
artículos
Título:
Crystal and Molecular Structure of 8-Acetamido-2,4,4,8-tetramethyl-3-aza-bicyclo 3.3.1 non-2-ene Perchlorate
Autor/es:
H. R. VITURRO; B. E. RIVERO; O. E. PIRO; J. CARAM; M. E. MARTINS; C. M. MARSCHOFF
Revista:
CANADIAN JOURNAL OF CHEMISTRY
Editorial:
NCR Research Press
Referencias:
Año: 1987 vol. 65 p. 2000 - 2003
ISSN:
0008-4042
Resumen:
X-ray single crystal analysis sheds further light on the structure of this new iminium salt. ATABNEP crystallizes in the monoclinic system, space group P21 and shows a very short value for the C-N distance in the iminium group, thus suggesting that the contribution of the carbonium ion form in this particular case is much lower than usual, a fact that can be considered a rationale for the reluctance of ATABNEP to undergo hydrolysis.
