INVESTIGADORES
PIRO Oscar Enrique
artículos
Título:
A complex containing three different kinds of Ru-N bonds: ethoxybis(nitrito)nitrosyl (N,N-tetramethylethylendiamine)ruthenium(II) complex
Autor/es:
P. ALBORES; L. M. BARALDO; E. E. CASTELLANO; O. E. PIRO; Z. D. CHAIA
Revista:
Acta Cryst. C
Editorial:
IUCr
Referencias:
Año: 2002 vol. 58 p. 235 - 236
Resumen:
The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.
