INVESTIGADORES
BONESI Sergio Mauricio
artículos
Título:
A study of substituent effect on 1H and 13C nmr spectra of mono, di and poly substituted carbazoles
Autor/es:
S. M. BONESI, M. A. PONCE, R. ERRA-BALSELLS
Revista:
JOURNAL OF HETEROCYCLIC CHEMISTRY
Editorial:
HeteroCorporation
Referencias:
Lugar: Tampa Florida; Año: 2005 vol. 42 p. 867 - 875
ISSN:
0022-152X
Resumen:
ABSTRACT: 1H and 13C NMR spectra of several substituted carbazoles (Series 1, 2, 3, 4 and 5) were measured. Substituent chemical shifts (SCS´s) and Lynch correlations of 1H and 13C nuclei were calculated and the substituent effect on the NMR phenomena was determined. Atomic charge densities for carbazoles of Series 1, 2, 3, 4 and 5 were calculated by using the semi empirical PM3 method. These values also show a linear correlation with the 13C chemical shifts.
