CIHIDECAR   12529
CENTRO DE INVESTIGACIONES EN HIDRATOS DE CARBONO
Unidad Ejecutora - UE
artículos
Título:
NUCLEOPHILIC NON-METAL ASSISTED TRIFLUOROMETHYLATION AND
Autor/es:
BARATA, SEBASTIAN; TORVISO, M.R.; BEATRIZ LANTAÑO; BONESI, SERGIO M.; AL POSTIGO
Revista:
JOURNAL OF FLUORINE CHEMISTRY
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 2014 vol. 161 p. 134 - 141
ISSN:
0022-1139
Resumen:
Nucleophilic trifluoromethylation and perfluoroalkylation reactions have been the outstanding approach during the last few decades to effect fluoroalkyl group addition or substitution reactions. In most instances, perfluoroalkyl-metal species participate at the beginning of the reactions. In this account, however, the latest nucleophilic non-metal assisted or uncatalyzed trifluoromethylation and perfluoroalkylation reactions of substrates bearing biological relevance will be discussed. 2014 Elsevier B.V. All rights reserved.