INVESTIGADORES
BONESI Sergio Mauricio
artículos
Título:
On the synthesis and isolation of chlorocarbazoles obtained by chlorination of N-sustituted carbazoles
Autor/es:
SERGIO M. BONESI, ROSA ERRA-BALSELLS
Revista:
JOURNAL OF HETEROCYCLIC CHEMISTRY
Editorial:
HeteroCorp
Referencias:
Lugar: USA; Año: 1997 vol. 34 p. 891 - 900
ISSN:
0022-152X
Resumen:
Chloro derivatives of N-methylcarbazole, N-phenylcarbazole, N-acetylcarbazole, N-benzoylcarbazole and 2-methoxy-N-methylcarbazole are synthesized. Some of them are described for the first time. By using semiempirical PM3 method theoretical substituent effects on the chlorinating reaction are calculated. A chlorination mechanism of carbazoles and N-substituted carbazoles are compared.