INVESTIGADORES
GARCIA EINSCHLAG Fernando Sebastian
artículos
Título:
Temperature effect on the hydrogen peroxide photolysis in aqueous solutions
Autor/es:
FERNANDO S. GARCÍA EINSCHLAG; MARIO R. FÉLIZ; ALBERTO L. CAPPARELLI
Revista:
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Referencias:
Año: 1997 p. 235 - 242
ISSN:
1010-6030
Resumen:
The photolysis of hydrogen peroxide in dilute aqueous solution (1 X 10-4 M) at various temperatures ( 15-85) and pH (2.5-7.0) was studied by flash photolysis. The rate of oxygen production under continuous photolysis conditions was measured at room temperature. The rate constants and activation parameters are reported. Evide ace for the formation of complexes between hydrogen pete xide andintermeate radicals is presented. The liquid phase data are discussed and compared with those available for the gas phase.