INVESTIGADORES
RODRIGUEZ TORRES Claudia Elena
artículos
Título:
Mössbauer Effect phase determination in iron oxide?polyaniline nanocomposites.
Autor/es:
J. C. APHESTEGUY; S. E. JACOBO; C. E. RODRÍGUEZ TORRES; M.B. FERNÁNDEZ VAN RAAP; F. H. SÁNCHEZ
Revista:
HYPERFINE INTERACTIONS
Editorial:
Springerlink
Referencias:
Año: 2008 vol. 179 p. 81 - 86
ISSN:
0304-3843
Resumen:
Mössbauer effect spectroscopy and thermal analysis techniques were applied to characterize polyaniline composites successfully synthesized by embedding Fe oxide nanoparticles (about 10?13 nm) in a polymeric matrix in the presence of dodecyl benzene sulfonic acid and HCl (dopant). Thermal techniques provided quantitative information on iron oxide content and on polyaniline stability and transformations. Mössbauer results indicated that for the whole studied composition range, 3.4 to 100 iron oxide wt.%, composites hold maghemite particles. A preliminary study of the conductivity of the nanocomposites was performed. The largest conductivity was observed for a wt.% maghemite composite where all particles are magnetically unblocked at room temperature within the Mössbauer time window.
