INVESTIGADORES
ROSSO Janina Alejandra
artículos
Título:
Reactions Of Sulphate And Phosphate Radicals With A, A, A- Trifluorotoluene
Autor/es:
ROSSO, JANINA A.; ALLEGRETTI, PATRICIA E; MÁRTIRE, DANIEL O.; GONZALEZ, MÓNICA C.
Revista:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Editorial:
RSC Publishing
Referencias:
Año: 1999 p. 205 - 210
ISSN:
0300-9580
Resumen:
The aqueous phase reactions of ,,-trifluorotoluene (TFT) with sulfate and phosphate radicals have been investigated by conventional flash-photolysis. The bimolecular rate constants obtained for the reactions of SO4, H2PO4, HPO4 and PO42 with TFT are (2 ± 1) × 107, (3.5 ± 0.5) × 107, (2.7 ± 0.5) × 106 and (9 ± 1) × 105M1 s1, respectively. The organic radicals produced from these reactions exhibit a common absorption peak at 290300 nm. Additionally, the transients generated from sulfate radicals show a shoulder at 360370 nm and those generated from phosphate radicals a less intense maximum at 400 nm. Based on the experimental results, the nature of the organic radicals is discussed. Additional information on the hydroxycyclohexadienyl radicals of TFT is obtained from independent experiments with hydrogen peroxide solutions containing TFT.