INVESTIGADORES
VACA CHAVEZ FORNASERO Fabian
artículos
Título:
On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate
Autor/es:
MARIA ISABEL CABAÇO; MARCEL BESNARD; FABIAN VACA CHAVEZ; NOËL PINAUD; PEDRO J. SEBASTIÃO; JOÃO A. P. COUTINHO; JOËLLE MASCETTI; YANN DANTEN
Revista:
CHEMICAL COMMUNICATIONS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2013 vol. 49 p. 11083 - 11085
ISSN:
1359-7345
Resumen:
Raman and NMR spectroscopies show that CS2 and OCS react spontaneously with 1-butyl-3-methylimidazolium acetate [C4mim] [Ac] in the liquid phase. The formation of [C4mim] CO2, [C4mim] COS, CH3COS and gaseous CO2 and OCS in both systems demonstrates that the anion plays an unexpected role not observed in the CO2?[C4mim] [Ac] reaction.
