CIHIDECAR 12529
CENTRO DE INVESTIGACIONES EN HIDRATOS DE CARBONO
Unidad Ejecutora - UE
artículos
Título:
Synthesis of a-D-Galf-(1-2)-D-galactitol and a-D-Galf-(1-2)[b-D-Galf-(1-3)]-D-galactitol, oligosaccharide derivatives from Bacteroides cellulosolvens glycoproteins
Autor/es:
LUCÍA GANDOLFI DONADÍO; GABRIEL GOLA; ROSA M. DE LEDERKREMER; CAROLA GALLO-RODRIGUEZ
Revista:
CARBOHYDRATE RESEARCH
Editorial:
Elsevier
Referencias:
Año: 2006 vol. 341 p. 2487 - 2497
ISSN:
0008-6215
Resumen:
ABSTRACT The synthesis of a-D-galactofuranosyl-(1-2)-D-galactitol, which has been isolated by reductive b-elimination from glycoproteins of Bacteroides cellulosolvens and Clostridium thermocellum, is described. The approach of selective glycosylation of an aldono-1,4-lactone by the thrichloroacetimidate method was employed. The synthesis of a-D-Galf-(1-2)[b-D-Galf-(1-3)]-D-Galol, that contains Galf units in both anomeric configurations is also reported. These are the first synthetic oligosaccharides with a-D-Galf, previously found in natural products
