INQUISAL 20936
INSTITUTO DE QUIMICA DE SAN LUIS "DR. ROBERTO ANTONIO OLSINA"
Unidad Ejecutora - UE
artículos
Título:
Monte Carlo simulation of the enantioseparation process
Autor/es:
VICTOR, BUSTOS; GIMENA ACOSTA; MARÍA ROXANA GOMEZ; VICTOR, PEREYRA
Revista:
PHYSICA A - STATISTICAL AND THEORETICAL PHYSICS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2012 vol. 391 p. 4389 - 4396
ISSN:
0378-4371
Resumen:
By means of Monte Carlo simulation, a study of enantioseparation by capillary electrophoresis has been carried out. A simplified system consisting of two enantiomers S (R)and a selector chiral C, which reacts with the enantiomers to form complexes RC (SC), has been considered. The dependence of delta mu(enantioseparation) with the concentration of chiral selector and with temperature have been analyzed by simulation. The effect of the binding constant and the charge of the complexes are also analyzed. The results are qualitatively satisfactory, despite the simplicity of the model.
