ALLYLIC OXIDATION OF a-PINENE OVER SUPPORTED SeO2-BASED CATALYSTS

FLORENCIA MUSSO; VICTORIA GUTIERREZ; MARÍA ALICIA VOLPE; MARÍA BELÉN FARAONI

LATIN AMERICAN APPLIED RESEARCH

PLAPIQUI(UNS-CONICET)

Lugar: Bahia Blanca; Año: 2022 vol. 53 p. 287 - 293

0327-0793

SeO2-based samples were tested for the oxidation of α-pinene and of benzil alcohol using ethanol as sol-vent. Commercial SeO2 was tested both at reflux and at 6 atm. of O2. At conversion level of approximately 40%, the yield of myrtenal was much higher in the latter case (34.4%) than under reflux (18.0%). A pal-ladium-promoted selenium dioxide-supported cata-lyst (Pd/SeO2/SiO2) was prepared. Characterization results indicated that selenium dioxide (14.4%) strongly interacts with silica support. The introduc-tion of palladium (0.98%) modifies the reducibility of SeO2, originating a selenium species activation to-wards allylic oxidation. A conversion level of 23% is attained over Pd/SeO2/SiO2 after 15 h of reaction time, using ethanol as solvent at 134°C the main product being myrtenal, obtained with a selectivity of 76%. Pd/SeO2/SiO2 allows to carry out a catalytic allylic oxidation of α-pinene, being the catalyst easy to handle and being possible its recovery and reuse after the reaction in liquid phase.