Synthesis and properties of trifluoromethoxyl fluoroformyl anhydride, CF3OC(O)OC(O)F

MARTIN D MANETTI; 1GUSTAVO A. ARGUELLO; MAXI A. BURGOS PACI

JOURNAL OF FLUORINE CHEMISTRY

ELSEVIER SCIENCE SA

Año: 2012 vol. 141 p. 16 - 20

0022-1139

In the present work the synthesis of the trifluoromethoxyl fluoroformyl anhydride is presented for the   first time. Two strategies were employed to obtain CF3OC(O)OC(O)F: the thermal decomposition of    CF3OC(O)OOOC(O)F in excess of CO, and the reaction between CF3OC(O)OOC(O)F, FC(O)OOC(O)F and CO.   A mechanism was proposed taking into account reaction rates and thermal stability of the intermediates.  DFT calculations at B3LYP/6-311+G* level were used to explore the conformational space of this molecule and the relative populations of conformers at room temperature, and to simulate the experimentalvibrational spectrum. This molecule completes the family of the asymmetric oxygen bonded acylcompounds CF3OC(O)?Ox?C(O)F with x = 1?3.