INVESTIGADORES
FRACAROLI Alejandro Matias
artículos
Título:
1D Supramolecular Assemblies That Crystallize and Form Gels in Response to the Shape-Complementarity of Alcohols
Autor/es:
FRACAROLI, ALEJANDRO M.; GROVER, GIRISHMA; OHTSU, HIROYOSHI; KAWANO, MASAKI; GÁNDARA, FELIPE; DE ROSSI, RITA H.; WEISS, RICHARD G.; TASHIRO, KENTARO
Revista:
LANGMUIR
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2023
ISSN:
0743-7463
Resumen:
N-9-Fluorenylmethyloxycarbonyl (Fmoc)- and C-tertiary butyl (t-Bu)-protected glutamate (L-2), bearing a phenanthroline moiety at the side residue, forms 1D supramolecular assemblies via H-bonding as well as undergoing π-stacking interactions to afford crystals or gels that depend onthe shape-complementarity of coexisting alcohols, as demonstrated by structural analyses on these assemblies by means of single-crystal X-ray diffractometry and supplemented with small- and wide-angle X-ray scattering data. Moreover, the rheological measurements on the gels help to define a model for when gels and crystals are expected and found. These observations and conclusions highlight an important, but not very appreciated, aspect of solute−solvent interactions within supramolecular assemblies that can allow the constituent-aggregating molecules in some systems to exhibit high selectivity toward the structures of their solvents. The consequences of this selectivity, as demonstrated here by single-crystal and powder X-ray diffraction data, can lead to self-assembled structures which alter completely the bulk phase properties and morphology of the materials. In that regard, rheological measurements have helped to develop a model to explain when gels and phase-separated mixtures of crystals and solvents are expected.